Invited paper for Prof. Naomichi Furukawa's 70th birthday Special Issue. Abstract: The ring opening of NH-aziridines with thiols was found to proceed in good yield at room temperature in the presence of an ionic liquid-butyl-3-methylimidazolium chloride (BMIM chloride).This mild methodology was applied to the synthesis of a camphor. TEMPO -Catalyzed Aerobic Oxidative Selenium Insertion Reaction: Synthesis of 3-Selenylindole Derivatives by Multicomponent Reaction of Isocyanides, Selenium Powder, Amines, and Indoles under Transition-Metal-Free Conditions. The Multiple Faces of Eugenol. A Versatile Starting Material and Building Block for Organic and Bio-Organic Synthesis and a Convenient. Aqueous work up or reaction with TBAF (fluoride ions) gives the desired product after desilylation. The enol ether double bond is epoxidized by the peracid. Relief of the epoxide ring strain drives the rearrangement with migration of the silyl group to give the silylated -hydroxy ketone product. A monosubstituted benzene, when treated with an electrophile, could undergo three electrophilic aromatic substitution reactions. Each reaction yields a disubstituted benzene as the organic product, which can be identified using the descriptors ortho, meta, and para (see ortho carbon). A any substituent.
Stereoselective synthesis Addition to Carbonyl Double Bonds. Stereoelectronic factors influence the addition of nucleophilic reagents to.
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